Belousov Zhabotinsky Reaction
㹺ҧ»¯Ô¡ÔÃÔÂÒà¤ÁÕ·ÕèÅѡɳоÔàÈɤ×Í ¤ÇÒÁà¢éÁ¢é¹¢Í§ species µèÒ§ æ ã¹»¯Ô¡ÔÃÔÂÒÊÒÁÒö
oscillate µÒÁàÇÅÒáÅÐ space ¹Õè¤×Í oscillating chemical reaction áÅж×Íà»ç¹Ë¹Öè§ã¹µÑÇÍÂèÒ§·ÕèÁÒ¨Ò¡¡Ò÷´Åͧ·ÕèàÂÕèÂÁ·ÕèÊØ´¢Í§
chaos áÅкҧ»ÃÒ¡¯¡Òóì·ÕèÁÕ¤ÇÒÁÊÑÁ¾Ñ¹¸ì¡Ñº nonlinear dynamic law à¾ÃÒÐÊÒÁÒö¤Çº¤ØÁ¡Ò÷´Åͧä´é§èÒ¡ÇèÒẺÍ×è¹
æ ·Ñé§·ÕèÁվĵԡÃÃÁ·Õè«Ñº«é͹ ¨Ö§¶Ù¡¹ÓÁÒãªéµÃǨÊͺ complex dynamical behavior
ÍÂèÒ§ chaos «Öè§à»ç¹µÑÇ¡Ó˹´ reaction dynamic
áÅл¯Ô¡ÔÃÔÂÒ·ÕèÁÕ¡Òà oscillation ·Õèà»ç¹·ÕèÃÙé¨Ñ¡áÅÐÈÖ¡ÉҡѹÁÒ¡·ÕèÊØ´¤×Í
Belousov-Zhabotinsky reaction ·Õè¤é¹¾ºâ´Â Boris Belousov ã¹»Õ 1958 áµèäÁèä´éÃѺ㹼ŧҹ¨¹äÁèÍÒ¨µÕ¾ÔÁ¾ìä´é
áÅéÇÁÕ Anatol Zhabotinsky¹ÓËÅÑ¡°Ò¹ÁÒÊÒ¹µèÍ ¨¹ÅºÅéÒ§¤ÇÒÁàª×èÍà¡èÒ æ ·Õè¼Ô´¾ÅÒ´¢Í§¹Ñ¡à¤ÁÕ·Õè¤Ô´ÇèÒµÑÇàͧ"
ÃÙé´Õ¡ÇèÒ" â´Â»®Ô¡ÔÃÔÂÒ¹ÕéÁÕª×èÍÂèÍ·ÕèÃÙé¨Ñ¡¡Ñ¹ÍÂèÒ§´ÕÇèÒ BZ reaction
BZ reaction à»ç¹»¯Ô¡ÔÃÔÂÒ oxidation ¢Í§ÊÒÃÍÔ¹·ÃÕÂìÍÂèÒ§ malonic acid ã¹ÊÒÃÅÐÅÒ¡ô·ÕèÁÕ
bromate ion ÍÂÙè¾ÃéÍÁ·Ñé§ metal catalyst ¤×Í Ce(III)/Ce(IV) áÅÐ [Fe(II)phen]2+/[Fe(III)phen]3+
(ferroin/ferriin)ËÅѧ¨Ò¡·ÕèãËéàÇÅÒ´Óà¹Ô¹ä» ÊÑ¡ÃÐÂШ¹à¡Ô´ oscillation ¢Öé¹â´ÂÁÕ
oscillatory wave à¡Ô´¢Öé¹â´Â¨ÐàËç¹ÊբͧÊÒÃÅÐÅÒÂà»ÅÕèÂ¹ä» ( àÁ×è;ԨÒóҷÕè¨Ø´ã´¨Ø´
˹Öè§ã¹ÊÒÃÅÐÅÒÂ) â´Â¨Ðà»ÅÕè¹ÃÐËÇèÒ§ÊÕá´§¡Ñº¹éÓà§Ô¹ ( ferroin/ferriin )à»ç¹ªèǧàÇÅÒ·Õèà»ç¹
periodic »ÃÐÁÒ³ 1 ¹Ò·Õ â´ÂÊÕ ·Õèà»ÅÕè¹仹Ñé¹à»ÅÕè¹仵ÒÁÍѵÃÒÊèǹ¤ÇÒÁà¢éÁ¢é¹¢Í§
ferroin ¡Ñº ferriin¹Ñé¹àͧ â´Â¡ÒÃÊÑ蹨дÓà¹Ô¹ä»àªè¹¹Õéä»ÍÕ¡»ÃÐÁÒ³ 2 ªÑèÇâÁ§¨¹äÁèàËÅ×Í¡ÒÃÊÑ蹢ͧ¤ÇÒÁà¢éÁ¢é¹
¹Ñ蹤×ÍÃкº¤èÍ æ à¢éÒÊÙèÊÁ´ØÅã¹áºº monotonic ãËéà»ç¹ä»µÒÁ»¯Ô¡ÔÃÔÂÒÃÇÁ¤×Í
3CH2(COOH)2
+ 2HBr + HBrO3 == 3CHBr(COOH)2 + 3H2O
áÅШ¹·éÒ·ÕèÊØ´¨Ðä´éà»ç¹ 3CH2(COOH)2+ 4HBrO3
==
4Br- + 9CO2
+ 6H2O â´Â¼èÒ¹ mechanism
·Õè«Ñº«é͹¹Ñ蹤×Í áÁé¨ÐÁÕ¡ÒÃoscillate ãËé¤ÇÒÁà¢éÁ¢é¹¢Í§
species ·ÕèÊӤѤ×Í malonic acid , bromate ¡ÅѺÁÒ ä´éµÒÁ period áµè¤ÇÒÁà¢éÁ¢é¹¢Í§
species àËÅèÒ¹Õé¡çÂѧ¤§Å´Å§ªéÒ æ ÍÂèÒ§µèÍ à¹×èͧµÒÁ¼Å¢Í§»¯Ô¡ÔÃÔÂÒÃÇÁ (
àÁ×è;ԨÒóҷÕè¨Ø´ æ ˹Öè§ã¹·Ø¡ªèǧ period )
áµè¡Òà oscillate ¢Í§¤ÇÒÁà¢éÁ¢é¹¢Í§ BZ reaction 㹡Ò÷´Åͧ·Õè condition
»¡µÔ¨ÐäÁèà»ç¹ chaos â´ÂµÑÇ»¯Ô¡ÔÃÔÂÒâ´ÂµÃ§ à¾ÃÒÐÊÑè¹à»ç¹ periodic áÅÐà¢éÒÊÙè
attractor »¡µÔ áµèÁÕ pattern formation ·ÕèÊÒÁÒöáÊ´§ÅѡɳТͧ chaos ÍÍ¡ÁÒä´é
ÊèÇ¹ã¹¡Ã³Õ BZ reaction ·Õè·Ó¡Ò÷´Åͧ㹠Contious-flow Stirred Tank Reactor
(CSTR) Íѹà»ç¹ÇÔ¸Õ·Õè¨ÐãË黯ԡÔÃÔÂÒ¤§ÍÂÙè¹Ò¹·ÕèÊØ´ ¡ÒÃÊÑ蹢ͧ¤ÇÒÁà¢éÁ¢é¹¨Ò¡
periodic¨Ðà¢éÒÊÙè unperiodic·Õèà»ç¹ chaos â´ÂµÃ§ã¹·ÕèÊØ´ «Öè§ã¹ CSTR BZ
reaction ¨Ð·ÓãËé pattern formation ·Õèä´éà»ç¹ÁÕÅѡɳТͧ chaos ÍÂèÒ§á¹è¹Í¹
áµè㹡ÒÃÈÖ¡ÉÒ BZ reaction 㹻Ѩ¨ØºÑ¹¹ÔÂÁãªé metal catalyst ÍÂèÒ§ Ru(bpy)32+/Ru(bpy)33+
á·¹ à¾ÃÒÐÊÒÁÒö illuminate ã¹ UV ä´é â´Â Ru(bpy)32+
¹Ñé¹ÁÕÊÕá´§áÅÐãËé
fluorescence ·Õè´Õ áµè Ru(bpy)33+ ÁÕÊÕà¢ÕÂÇáµèäÁèÁÕ
fluorescence ·ÕèÁÕ»ÃÐ⪹ìÍÂèÒ§ÂÔè§ã¹¡ÒÃÈÖ¡ÉÒ excitable media ¢Í§ BZ reaction
µÑÇÍÂèÒ§ concentration wave ·Õèà¡Ô´¢Öé¹ã¹ BZ reaction